2025 AOCS Annual Meeting & Expo.
Surfactants and Detergents
Donald H. Champion, PhD (he/him/his)
Research Fellow
Indorama Ventures
The Woodlands, Texas, United States
Recent regulatory mandates now limit 1,4-dioxane levels in consumer products to no more than 1 ppm. These stringent requirements have extended to surfactant suppliers, presenting significant challenges, particularly for alkyl ether sulfates. During the sulfation process, 1,4-dioxane formation occurs as the poly(ethyleneoxy) chain of surfactant precursors or ether sulfates are exposed to acidic conditions. This reaction involves the cyclization of two contiguous ethyleneoxy groups, generating 1,4-dioxane as a byproduct.
Efforts to meet these regulatory standards have necessitated complex and costly post-treatment processes to reduce 1,4-dioxane levels to less than 5 ppm. Consequently, many consumer product companies have moved away from these versatile surfactants, often adopting less effective or more expensive alternatives.
In this presentation, we will discuss our work on evaluating alternative precursors to traditional ether sulfates. These innovative alternatives eliminate 1,4-dioxane formation during sulfation, offering a compliant and efficient solution for manufacturers. Join us as we explore how these advancements can address the 1,4-dioxane challenge while maintaining performance in consumer product formulations.